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© 1999 Oxford University Press

Article

Arene dioxides of substituted pyrenes: synthesis and X-ray structural studies

Robert W. Murray1, Megh Singh and Nigam P. Rath

Department of Chemistry, University of Missouri—St Louis, 8001 Natural Bridge Road, St Louis, MO 63121, USA

The arene dioxides of five 1-substituted pyrenes have been synthesized using dimethyldioxirane. The diasteroisomeric distribution of the dioxides has been determined. X-ray crystallographic structures of the dioxides have also been obtained. These structures show that for the cis dioxides the molecular structures show a departure from planarity, the extent of which is dependent on the substituent.


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